Józef H. Wiora, PhD, DSc, Eng.

my publications

Publications and Presentations

1. **Faisal Saleem, Józef Wiora.** *Kernelized PCA-Based Reduced-Order Linear Parameter Varying (LPV) Modelling of Twin Rotor Aerodynamic System. *XXV International Student Scientific Session "Materials and Technologies of the 21st Century", Katowice (Poland), 16.05.2024.

2. **Faisal Saleem, Józef Wiora.** *Applicability of Fractional-Order PID Controllers for Twin Rotor Aerodynamic System Objects. *Automation 2024, Warszawa (Poland), 08-09.05.2024.

``Particulate matter (PM) suspended in the air significantly impacts human health. Those of anthropogenic origin are particularly hazardous. Poland is one of the countries where the air quality during the heating season is the worst in Europe. Air quality in small towns and villages far from state monitoring stations is often much worse than in larger cities where they are located. Their residents inhale the air containing smoke produced mainly by coal-fired stoves. In the frame of this project, an air quality monitoring network was built. It comprises low-cost PMS7003 PM sensors and ESP8266 microcontrollers with integrated Wi-Fi communication modules. This article presents research results on the influence of the PM sensor location on their indications. It has been shown that the indications from sensors several dozen meters away from each other can differ by up to tenfold, depending on weather conditions and the source of smoke. Therefore, measurements performed by a network of sensors, even of worse quality, are much more representative than those conducted in one spot. The results also indicated the method of detecting a sudden increase in air pollutants. In the case of smokiness, the difference between the mean and median indications of the PM sensor increases even up to 400 µg/m3 over a 5 min time window. Information from this comparison suggests a sudden deterioration in air quality and can allow for quick intervention to protect people’s health. This method can be used in protection systems where fast detection of anomalies is necessary."

``In recent years, the usage of fractional-order (FO) differential equations to describe objects and physical phenomena
has gained immense popularity. Due to the high computational complexity in the exact calculation of these equations,
approximation models make the calculations executable. Regardless of their complexity, these models always introduce
some inaccuracy which depends on the model type and its order. This article shows how the selected model
affects the obtained solution. This study revisits seven fractional approximation models, known as the Continued
Fraction Expansion method, the Matsuda method, the Carlson method, a modified version of the Stability Boundary
Locus fitting method, and Basic, Refined, and Xue Oustaloup filters. First, this work calculates the steady-state values
for each of the models symbolically. In the next step, it calculates the unit step responses. Then, it shows how the
model selection affects Nyquist plots and compares the results with the plot determined directly. In the last stage, it
estimates the trajectories for an example of an FO control system by each model. We conclude that when employing
approximation models for fractional integro-differentiation, choosing the appropriate type of model, its parameters,
and order is very important. Selecting the wrong model type or wrong order may lead to incorrect conclusions when
describing a real phenomenon or object."

5. **Wojciech Batko, Rafał Burdzik, Jan Warczek, Leszek Radziszewski, Tomasz Korbiel, Bartłomiej Stępień, Artur Nowoświat, Józef Wiora, Andrzej Bąkowski, Zbigniew Skrobacki.** *Analiza zmian czułości skali decybelowej dla rożnych zakresów wartości granicznych pomiarów środowiskowych. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 85, Politechnika Śląska, 2022.

6. **Wojciech Batko, Leszek Radziszewski, Rafał Burdzik, Tomasz Korbiel, Bartłomiej Stępień, Jan Warczek, Artur Nowoświat, Andrzej Bąkowski, Zbigniew Skrobacki, Józef Wiora, Paweł Fotowicz.** *Zastosowanie algebry decybelowej w ocenach stanu zagrożeń akustycznych środowiska - nowe zadania projektu badawczego. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 86-87, Politechnika Śląska, 2022.

7. **Tomasz Korbiel, Bartłomiej Stępień, Jacek Wierzbicki, Józef Wiora, Rafał Burdzik, Jan Warczek, Artur Nowoświat, Wojciech Batko, Radosław Kruk, Leszek Radziszewski, Andrzej Bąkowski, Zbigniew Skrobacki.** *Przegląd możliwości kierunkowego pomiaru zagrożenia akustycznego. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 88-89, Politechnika Śląska, 2022.

8. **Artur Nowoświat, Wojciech Batko, Tomasz Korbiel, Bartłomiej Stępień, Rafał Burdzik, Jan Warczek, Leszek Radziszewski, Andrzej Bąkowski, Zbigniew Skrobacki, Józef Wiora.** *Algebra liczb perturbacyjnych. Zastosowanie w akustyce i szacowaniu niepewności. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 90, Politechnika Śląska, 2022.

9. **Bartłomiej Stępień, Wojciech Batko, Tomasz Korbiel, Rafał Burdzik, Jan Warczek, Józef Wiora, Artur Nowoświat, Leszek Radziszewski, Andrzej Bąkowski, Zbigniew Skrobacki, Radosław Kruk.** *Wykorzystanie metod statystycznych do wyznaczania poziomu mocy akustycznej maszyn i urządzeń. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 91, Politechnika Śląska, 2022.

10. **Jan Warczek, Rafał Burdzik, Wojciech Batko, Tomasz Korbiel, Bartłomiej Stępień, Józef Wiora, Artur Nowoświat, Leszek Radziszewski, Andrzej Bąkowski, Zbigniew Skrobacki.** *Koncepcja zastosowania mocy pola akustycznego jako miary zagrożenia hałasem. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 92, Politechnika Śląska, 2022.

11. **Józef Wiora, Wojciech Batko, Tomasz Korbiel, Bartłomiej Stępień, Rafał Burdzik, Jan Warczek, Artur Nowoświat, Radosław Kruk, Leszek Radziszewski, Andrzej Bąkowski, Zbigniew Skrobacki.** *Paradoks określania niepewności pomiaru wielkości logarytmicznej na przykładzie poziomu hałasu. * ISBN 978-83-964252-0-1, Peruń Grzegorz, Konieczny Łukasz (red.): Diagnostyka Maszyn. XLVIII Ogólnopolskie Sympozjum, Wisła, 27.02-2.03. 2022. Streszczenia, p. 93, Politechnika Śląska, 2022.

12. **Józef Wiora.** *Least Lp-norm low-pass filter. *Automatica, 133, (11) p. 109854, 2021.

``We know that least Lp-norm filters, processing a one-dimensional signal within a time window, are suitable for attenuation of impulses. This article proposes a new analogue filter with exponentially weighted old samples, which is a generalization of the first-order low-pass filter. The obtained formula describing the output signal is presented in an implicit form. A simple but always convergent algorithm facilitates the approximation of the signal. Conducted simulations show properties of a set of the analogue filters with different values of p in the range of 1 to 2, covering step, ramp, and sinusoidal responses, as well as the ability to attenuate random noises, including stable distributions. The results prove that the elaborated filters achieve steady states faster than the typical low-pass filter and are particularly useful in the suppression of impulses. This property makes it possible that such a filter is perfectly adequate as an input filter of measurement transducers.
"

``The growing popularity of ESP boards has led to the development of several programming platforms. They allow users to develop applications for ESP modules in different programming languages, such as C++, C, Lua, MicroPython, or using AT Commands. Each of them is very specific and has different advantages. The programming style, efficiency, speed of execution, level of advancement, or memory usage will differ from one language to another. Users mostly base their choice depending on their programming skills and goals of the planned projects. The aim of this work is to determine, which language is the best suitable for a particular user for a particular type of project. We have described and compared the mentioned languages. We have prepared test tasks to indicate quantified values. There is no common rule because each of the languages is intended for a different kind of user. While one of the languages is slower but simpler in usage for a beginner, the other one requires broad knowledge but offers availability to develop very complex applications.
"

``Fractional-order (FO) differential equations are more and more frequently applied to describe real-world applications or models of phenomena. Despite such models exhibiting high flexibility and good fits to experimental data, they introduce their inherent inaccuracy related to the order of approximation. This article shows that the chosen model influences the dynamic properties of signals. First, we calculated symbolically the steady-state values of an FO inertia using three variants of the Oustaloup filter approximation. Then, we showed how the models influence the Nyquist plots in the frequency domain. The unit step responses calculated using different models also have different plots. An example of FO control system evidenced different trajectories dependent on applied models. We concluded that publicized parameters of FO models should also consist of the name of the model used in calculations in order to correctly reproduce described phenomena. For this reason, the inappropriate use of FO models may lead to drawing incorrect conclusions about the described system."

The purpose of an automatic control is to provide the best quality of the output signal of a controlled object. This quality is dependent on the type and tuning parameters of the used controller and on the properties of a transducer measuring the output signal. In this work, it was considered how the imperfections of the transducer propagate by the fractional-order (FO) control system. It was revealed that the assumed approximation method of FO derivation changes the trajectory of the output signal and also has an influence on the steady-state value. In turn, the measurement uncertainty estimation should take into account the analysis of the occurrence of oscillations, arising from drifts of imperfect components, that may exceed the permissible errors of the measuring transducer.

18. **Józef Wiora.** *Poziomomierze. * ISBN 978-83-7880-688-2, Alicja Wiora: Przemysłowe pomiary wielkości fizycznych i chemicznych, p. 86–93, 843, Politechnika Śląska, 2020.

19. **Józef Wiora.** *Konduktometria i amperometria. * ISBN 978-83-7880-688-2, Alicja Wiora: Przemysłowe pomiary wielkości fizycznych i chemicznych, p. 106–113, 843, Politechnika Śląska, 2020.

20. **Józef Wiora.** *Poziomomierze. * ISBN 978-83-7880-688-2, Alicja Wiora: Przemysłowe pomiary wielkości fizycznych i chemicznych, p. 221–223, 843, Politechnika Śląska, 2020.

21. **Józef Wiora.** *Konduktometria i amperometria. * ISBN 978-83-7880-688-2, Alicja Wiora: Przemysłowe pomiary wielkości fizycznych i chemicznych, p. 227–230, 843, Politechnika Śląska, 2020.

23. **Józef Wiora, Alicja Wiora.** *Steady-state errors in closed-loop control systems with fractional-order PID controllers. *11th International Conference on Non-Integer Order Calculus and Its Applications RRNR, Częstochowa (Poland), 12-13.09.2019.

24. Patent Application No. P.430738, EP19189219, US16527083. **Maciej Borówka, Artur Kłosowski, Marek Pawełczyk, Andrzej Kozyra, Tomasz Grychowski, Stanisław Wrona, Józef Wiora.** *The method and system for controlling of heating, ventilation and air conditioning. *30.07.2019.

``Glass pH electrodes are still successfully applied in the chemical and environmental industry. During their long-term use, periodic calibration is required to maintain the required accuracy of measurements because the parameters of the electrodes change over time. This work presents an aging of 11 pH electrodes within approximately 600 days in tap water. During this period, potentials of all electrodes in five buffer solutions were measured 44 times. This allowed determining the aging models of the electrodes. Models in other mediums might be different. Changes in slope, standard potential, hysteresis, and linearity of the characteristics were the objects of observations. A method for predicting electrode parameters is proposed. Furthermore, the procedure for estimating the uncertainty of pH measurements considering the aging of the electrodes is described. As a result of this work, a model of the aging process of pH electrodes in tap water can be constructed and subsequently, the measurement accuracy in the periods between calibrations can be improved."

``Evaluation of measurement uncertainties covers uncertainty propagation from sources to a measured quantity. Phenomena taking place inside measuring transducers are typically considered applying Type B evaluation. It is evidenced in this work, that transducers included in a closed-loop control system should be treated in a different way because their uncertainty sources propagate through the dynamic system and change their limits of variabilities. Depending on frequencies, the limits may be either similar or lower or even higher. An especially dangerous case takes place when the variability at the output of the plant is greater than at the output of the transducer. In this work, such cases are presented and discussed."

27. **Józef Wiora, Alicja Wiora.** *Propagation of measurement uncertainties through an integer or fractional order automatic control regulation system (in Polish). *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Kędzierzyn-Koźle, 5.10.2018.

28. **Józef Wiora, Alicja Wiora.** *Problems related to the propagation of measurement uncertainties through a closed-loop fractional-order control system. *10th International Conference on Non-Integer Order Calculus and Its Applications, Białystok (Poland), 20-21.09.2018.

``An assessment of measurement uncertainty is a task, which has to be the final step of every chemical assay. Apart from a commonly applied typical assessment method, Monte Carlo (MC) simulations may be used. The simulations are frequently performed by a computer program, which has to be written, and therefore some programming skills are required. It is also possible to use a commonly known spreadsheet and perform such simulations without writing any code. Commercial programs dedicated for the purpose are also available. In order to show the advantages and disadvantages of the ways of uncertainty evaluation, i.e., the typical method, the MC method implemented in a program and in a spreadsheet, and commercial programs, a case of pH measurement after two-point calibration is considered in this article. The ways differ in the required mathematical transformations, degrees of software usage, the time spent for the uncertainty calculations, and cost of software. Since analysts may have different mathematical and coding skills and practice, it is impossible to point out the best way of uncertainty assessment—all of them are just as good and give comparable assessments."

30. **Józef Wiora, Alicja Wiora.** *Measurement uncertainty evaluation of results provided by transducers working in control loops. *23rd International Conference on Methods and Models in Automation and Robotics (MMAR 2018), Miedzyzdroje (Poland), 27–30.08.2018.

31. Polish Patent Application No. P.423032. **Józef Wiora, Alicja Wiora.** *Układ z elektrodą odniesienia z połączeniem ciekłym do pomiarów elektroanalitycznych podpowierzchniowych i głębinowych. *02.10.2017 - Publ.: --.--.20--.

``In this article, a project of an unmanned aerial vehicle (UAV) equipped with a measurement head designed for monitoring of air pollution is presented. The head contains modern sensors selective to the most important components of air in view of environmental pollution. Measurement data are acquired locally as well as transmitted wirelessly to a ground station. The UAV may be programmed to a particular measurement missions. The ground station dispose of a software for flight control and for visualisation of measurement results on-line."

``This paper describes a way of determining selected water parameters using a prototype of a remote-controlled catamaran. The remote controlling allows to steer the boat and to manage the measurement process from the shore. It is possible to monitor the water parameters online as well as to store them and analyze them afterwards. The measured parameters are determined mainly using potentiometric methods and include several ion concentrations. The system is orientated towards monitoring breeding ponds or other similar surface waters. The mechanical construction of the catamaran, its electronic circuits and implemented software are described in detail in the paper. Conclusions obtained from preliminary tests are also included. The described construction allows analysts to perform simple and inexpensive remote measurements or assessments of water quality and reduces the time of such analysis in comparison to traditional sampling."

``Acoustic insulation of a device from the environment can be enhanced by appropriate control of its casing vibrations.
The level of noise reduction obtained in such way is considered as the main point for evaluating the performance of the active control system, hence its appropriate measurement constitutes a vital issue.
In this study, measurement uncertainty evaluation of the sound pressure level difference is presented.
Three independent components of the Type A evaluated uncertainties are derived.
Many sets of conducted experiments allow to estimate the components, while information read from the calibration certificate of the employed sound level meter allow to estimate the Type B components.
Prepared uncertainty budgets show that the most contributing source is the location dependency.
Recommendations for appropriate performance measurement of an active control system are stated basing on the obtained results.
"

``The term “Internet of things,” despite the lack of commonly acceptable definition, is now often used, mainly for marketing purposes, by manufacturers of various types of equipment. This article shows how to understand this term based on the recommendations of the International Telecommunication Union (ITU), and gives properties of the discussed technology. Implementation of the technology to a pH measurement transmitter is also described and results of laboratory tests are presented."

→ Get pdf``According to recent findings, it is possible to computationally determine a measurement
result (value and uncertainty), using a special measurement method, in which this uncertainty
is less than that assessed directly from experiments using Type B evaluation. The method
works well only if the quantity is additive and its uncertainty is constant, i.e. independent
of the measurement value. In the paper, a generalisation is made that also allows for the
application of similar reasoning to quantities with variable uncertainties. The generalisation
is obtained thanks to the replacement of the least squares optimisation, used in the derivation
of the first method, with the weighted least squares. Examples with models of quantities that
have variable uncertainties are described to show circumstances where improvements are
significant. It can be said that the method described always improves uncertainties of additive
quantities, but the improvement is not always significant. Suggestions to obtain the best
improvement are given according to the analysis performed. A real laboratory experiment
of a resistance measurement, with its uncertainty dominated by current measurement, was
conducted to show how the method works."

``Parameters of a model describing a measurement process obtained during a calibration experiment allow one to calculate a measurement result, but a simple estimation of measurement uncertainties of the parameters is not sufficient to assess the uncertainty of the result.
In this paper, an example of a pH measurement conducted using an ion-selective electrode is presented, in which the uncertainty is evaluated taking into consideration the existing correlation between the parameters of the electrode.
The calculations apply either covariances or correlation coefficients that have to be computed additionally.
The example presented in this paper illustrates that there are some problems with rounding of variables which, because of the existing very strong correlations, significantly changes the sought uncertainty.
This approach is compared with other approaches, that is, usage of uncorrelated variables and Monte Carlo simulations that are described in an earlier work.
It is concluded that the approach of uncertainty evaluation, in which covariances or correlation coefficients are explicitly calculated, is work-consuming and may cause significant discrepancies between correct and obtained assessments if some roundings or approximations are done, or if the correlation coefficient is obtained experimentally based on data including random errors.
"

39. **Andrzej Kozyra, Sebastian Patałąg, Alicja Wiora, Józef Wiora.** *Estimation of radioactive concentration of radon and its derivatives (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (39–40) p. Dodatek 21–22, 2016.

40. **Józef Wiora.** *Metrological problems associated with electrochemical measurement of fluid composition (in Polish). *Seminarium Instytutu Automatyki, Gliwice, 10.11.2015.

The paper deals with the problem of ion activity determination for a mixture by means of ion-selective electrodes.
Mathematical model of the analysed phenomenon is described by the Nicolsky-Eisenman equation, which relates activities of ions and ion-selective electrode potentials.
The equation is strongly nonlinear and, especially in the case of multi-compound assays, the calculation of ion activities becomes a complex task.
Application of multilayer perceptron artificial neural networks, which are known as universal approximators, can help to solve this problem.
A new proposition of such network has been presented in the paper.
The main difference in comparison with the previously proposed networks consists in the input set, which includes not only electrode potentials but also electrode parameters.
The good network performance obtained during training has been confirmed by additional tests using measurement results and finally compared with the original as well as the simplified analytical model.

Determination of pH using a typical glass electrode requires prior calibration in order to determine the electrode parameters.
Knowledge about uncertainties of the parameters is insufficient to calculate the uncertainty of measured pH because of existing correlation.
In the paper, an example illustrating the problem is presented.
Two ways of proper uncertainty assessment are suggested:
(1) analytical with removing the correlated variables and (2) numerical using Monte Carlo simulations.
The second one seems to be much less time-consuming and allows easier investigations of the uncertainty properties.

43. **Józef Wiora, Dariusz Grabowski, Alicja Wiora, Andrzej Kozyra.** *Application of artificial neural networks for modelling of Nicolsky-Eisenman equation and determination of ion activities in mixtures. *7th IEEE International Conference on Intelligent Systems IS’14, Warsaw, 24-26.09.2014.

44. **Józef Wiora.** *Uncertainty evaluation of pH measured using potentiometric method. *7th IEEE International Conference on Intelligent Systems IS’14, Warsaw, 24-26.09.2014.

``A common technique applied during an assay is averaging several repeated measurements in order to obtain a more accurate result.
This approach is suitable for most applications.
However, in the case of impulsive disturbances which affect the measured object, averaging is not optimal.
In the paper, the properties of impulsive disturbances are described and it is explained why averaging is suitable for Gaussian disturbances and unsuitable for impulse ones.
The iteratively reweighted least squares method, popular among researchers dealing with signal processing, has been simplified, allowing analysts to use it easily, and it has been adopted to calculate a weighted mean which is more reliable.
The properties of the weighted mean have been determined based on Monte Carlo simulations and an analytical signal obtained from an ion-selective electrode.
The results shown that the
most reliable results are obtained when the average is replaced by such weighted mean, which reduces to the median filtration---then,
the obtained results are in some cases a bit worse but far less sensitive to impulses."

46. **Józef Wiora.** *Ch. 8. Measurements with digital oscilloscope, in: Laboratory of Metrology Fundametals (red. D. Buchczik, S. Waluś). * , Wydawnictwo Politechniki Śląskiej, Gliwice 2014. ISBN: 978-83-7880-163-4

47. **Andrzej Kozyra, Adrian Hamczyk, Alicja Wiora, Józef Wiora,.** *Floating platform for environmental measurements (in Polish)?. *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (36/38) 2014.

48. **Andrzej Kozyra, Alicja Wiora, Józef Wiora,.** *Uncertainty assessments of multicompound potentiometric measurements conducted using ADDA2 ionmeter (in Polish)?. *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (36/38) 2014.

49. **Józef Wiora.** *Application of the IRLS algorithm to determine the weighted mean of signal disturbed by impulsive noise (in Polish)?. *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (36/38) 2014.

50. **Józef Wiora.** *What is the Combined measurements method (in Polish)?. *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (36/38) 2014.

51. **Józef Wiora.** *Automation of a calibration process of ion selective electrodes (in Polish)?. *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (36/38) 2014.

53. **Józef Wiora.** *Application of the IRLS algorithm to determine the weighted mean of signal disturbed by impulsive noise (in Polish)?. *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Częstochowa, 15.11.2013.

54. **Józef Wiora, Andrzej Kozyra, Alicja Wiora.** *What is the Combined measurements method (in Polish)?. *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Gliwice, 28.06.2013.

``The commented article has introduced to metrology a new way of lowering the uncertainty assessed using Type B evaluation.
The proposed method operates properly under some assumptions but unfortunately, the idea has been presented with some understatements and mistakes.
The weak points are shown and discussed in this article."

``This paper presents a research installation for developing flow measurements in open channel.
A tracer technique is used where sodium chloride is applied as a tracer and a conductometric cell as a tracer sensor.
Properties of the applied electrical measuring circuit, the ways of determining tracer transit time, flow rate and flow velocity are described.
From conducted experiments, the expanded measurement uncertainty of flow rate is assessed as less then 6%."

57. **Andrzej Kozyra, Adrian Hamczyk, Alicja Wiora, Józef Wiora,.** *Floating platform for environmental measurements (in Polish)?. *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Gliwice, 30.11.2012.

``In this paper a novel calibration procedure for the parameter determination of ion-selective electrodes used in an array is described. Commonly used procedures require a large number of standards to determine the parameters based on the Nicolsky–Eisenman model.
The elaborated procedure reduces the number of standards to a minimum by using a standard containing a mixture of ions instead of a couple of pure standards.
This paper presents a complete calibration procedure, which consists of designing the composition of the standards, parameter determination and verification of the calibration results.
Comparison of the results obtained by the procedure presented with results obtained by the Two-Point Calibration and Separate Solution methods proves that the accuracies of both procedures are comparable.
The outlined procedure can be applied in multicomponent analysers."

59. **Alicja Wiora, Andrzej Kozyra, Józef Wiora.** *Calibration of ion-selective electrodes with a reduced number of standards (in Polish). *Seminarium Instytutu Automatyki, Gliwice, 26.03.2012.

60. **Józef Wiora, Alicja Wiora, Andrzej Kozyra.** *Automation of a calibration process of ion selective electrodes (in Polish)?. *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Częstochowa, 09.12.2011.

62. **Andrzej Kozyra, Alicja Wiora, Józef Wiora.** *Uncertainty evaluation of multicompound potentiometric measurement (in Polish)?. *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Gliwice, 29.06.2011.

63. **Alicja Wiora, Józef Wiora, Andrzej Kozyra.** *Teaching of solution conductance measurements (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (34-35) p. 249--250, 2011.

64. **Józef Wiora, Andrzej Kozyra, Alicja Wiora.** *Another way of calibration of ion-selective electrodes (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (34-35) p. 232--235, 2011.

65. **Andrzej Kozyra, Alicja Wiora, Józef Wiora.** *Ion-meter for multi-compound measurements (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (34-35) p. 206--208, 2011.

66. **Alicja Wiora, Józef Wiora, Andrzej Kozyra.** *Teaching of solution conductance measurements (in Polish). *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Gliwice, 26.11.2010.

67. **Józef Wiora.** *The application of a spreadsheet in the uncertainty evaluation using Monte Carlo method in the case of ion-selective electrodes (in Polish). *VIII Polska Konferencja Chemii Analitycznej, p. 211, Kraków, 04-09.07.2010.

68. **Józef Wiora, Dawid Sawielew, Alicja Wiora, Andrzej Kozyra.** *The impact of the activity coefficient on the multi-component potentiometric measurement of ion concentration (in Polish). *VIII Polska Konferencja Chemii Analitycznej, p. 227, Kraków, 04-09.07.2010.

69. **Józef Wiora, Wojciech Błotnicki, Alicja Wiora, Rafał Kleszczewski.** *Application of conductivity measurement in the determination of flow value using the marker method (in Polish). *VIII Polska Konferencja Chemii Analitycznej, p. 438, Kraków, 04-09.07.2010.

70. **Alicja Wiora, Józef Wiora, Andrzej Kozyra, Tomasz Grychowski.** *Conception of a point-of-care device for monitoring the patient's health (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (33) p. 133--136, 2009.

71. **Józef Wiora, Andrzej Kozyra, Alicja Wiora.** *Another way of calibration of ion-selective electrodes (in Polish). *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Częstochowa, 27.11.2009.

72. **Andrzej Kozyra, Józef Wiora, Alicja Wiora.** *Ion-meter for multi-compound measurements (in Polish). *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Opole, 19.06.2009.

73. **Józef Wiora.** *Another way of calibration of ion-selective electrodes. A review (in Polish). *Seminarium Instytutu Automatyki, Gliwice, 09.12.2008.

74. **Alicja Wiora, Józef Wiora, Andrzej Kozyra, Tomasz Grychowski.** *Conception of a point-of-care device for monitoring the patient's health (in Polish). *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Gliwice, 05.12.2008.

``The response time of ion-selective electrodes (ISEs) is especially essential when measurements are performed for diluted solutions. The time needed to archive the steady-state E2 can be measured in minutes.
The developed algorithm shorten the time significantly by using the estimated value of E2. The dynamic error is then reduced 2-6 times, depending on model applied to describe the dynamic properties of ISE, on disturbances and on correctness of choice of the dynamic parameters.
Real measuring data used in tests prove that the best model applied to the prediction of E2 value is Rechnitz-Hameka model."

``In the paper, the evaluation of uncertainty in concentration measurement based on the cause and effect diagram is presented.
Two methods of evaluating the uncertainty of calibration parameters of ion-selective electrode are compared: the GUM method and the Monte Carlo method. Values obtained in examples are very similar.
Small differences are visible for larger values of input data uncertainties.
It is caused by the change of the probability distribution shape when the function is non-linear.
The comparison covers the possibility of determination the final value and its uncertainty, the necessity of derivation of the parameters and sensitivity coefficients formulae, the possibility of analyzing the contributions, of making histograms and of taking into considerations nonlinearities.
Using the Monte Carlo method, the concentration uncertainties are evaluated for example data."

``Measured values of dynamic parameters of ion-selective electrodes are dependent i.a. on the research methods applied due to difficulties in the proper realization of the ion activity change at the electrode membrane. In the paper, the new measuring set-up, realizing the activity step, is presented.
Two jets, controlled by the electric valves, through those solutions having different activities are flowed, are applied in the set-up.
Basing on the results obtained experimentally, it can be stated that the activity change is enough rapid. Furthermore, the electric circuit is not opened during the change of the activities what is a drawback of some methods."

78. **Andrzej Kozyra, Alicja Wiora, Józef Wiora.** *Uncertainty evaluation for potentiometric measurements (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (32) p. 109--112, 2008.

``The relationship between the potential E of the ion-selective electrode and ion concentration c are presented in the paper – eqs. (1) – (5).
The operations needed to prepare an activity standard, basing on eqs. (7) – (10), are listed and an example is given, haw to make it.
Basing on eq. (11), linking concentration c, mass of salt m* and volume of solution V, the relative concentration uncertainty ur(c) is derived – eq. (12), and using a scale and non-ideal salt not having 100% content (cont) of substance of interest, the eq. (14) is obtained.
After dilutions – eq. (15), concentration uncertainty changes – eq. (17).
The next example is placed illustrating the change.
The concentration uncertainties of standards obtained using multiple dilution method implemented on the automatic system SAWCEJS [5] are calculated in sec. 4."

80.

81. **Józef Wiora.** *Characterisation of measuring errors caused by simplifications of physicalchemical phenomena in multicomponent ion-selective measurements (in Polish). *Works of Scientific Commissions, The Katowice Branch of the Polish Academy of Science, (31/2006) p. 100--102, 2007.

82. **Józef Wiora, Alicja Wiora.** *Uncertainty propagation in potentiometric measurement of ion concentration in multicomponent mixture (in Polish). *IV Sympozjum nt. Metrologiczne właściwości programowalnych przetworników pomiarowych, Gliwice, 19--20.11.2007.

83. **Józef Wiora.** *Uncertainty evaluation of calibration parameters in potentiometric ion-selective electrodes in simulating way (in Polish). *IV Sympozjum nt. Metrologiczne właściwości programowalnych przetworników pomiarowych, Gliwice, 19--20.11.2007.

84. **Alicja Wiora, Józef Wiora, Przemysław Pacak.** *Decreasing in dynamic error of ion-selective electrode by prediction of steady-state value of potential (in Polish). *IV Sympozjum nt. Metrologiczne właściwości programowalnych przetworników pomiarowych, Gliwice, 19--20.11.2007.

85. **Andrzej Kozyra, Alicja Wiora, Józef Wiora.** *Uncertainty evaluation for potentiometric measurements (in Polish). *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Opole, 20.04.2007.

86. **Józef Wiora.** *Charakterystyka błędów pomiarowych spowodowanych uproszczeniem modeli zjawisk fizykochemicznych w wieloskładnikowych pomiarach potencjometrycznych. *Meeting of the Polish Academy of Sciences, Katowice Branch, Commission of Metrology, Gliwice, 8.12.2006.

The plot of ion-selective electrode's potential vs. ion concentration in a solution is non-linear and very complex. In the paper, a set-up is described which allows to determine the plot using multiple dilution method in an automatic way. The set-up is not expensive and the presence of experimenter in the laboratory is not necessary during the test of the electrode. Additionally, the system allows for simultaneous investigation of several electrodes.

``Dynamic models of an ion-selective electrode are analysed in this article taking into account the independence of values of its dynamic parameters from the value and direction of activity change.
Unfortunately, a complicated mathematical representation of a new model makes the model difficult to be applied in practice.
Therefore, some simplifications are made constructing two semi-empirical models: 1) a model with the k parameter and 2) a model basing on two other models well-known from the literature.
Verifications of the new models have been performed using the measuring set-up built in the Division of Measurement Systems at the Silesian University of Technology.
Obtained results proved that the model with the k parameter completely fulfils the goal of the article − its dynamic parameters are dependent on the slightest degree of the kind of activity step."

89.

90. **Alicja Wiora, Józef Wiora.** *Właściwości dynamiczne elektrod jonoselektywnych. *IX Konferencja Naukowa Czujniki Optoelektroniczne i Elektroniczne, p. 255--258, Zakopane, 19--22.06.2006.

91. **Józef Wiora, Alicja Wiora.** *System umożliwiający automatyczne wyznaczanie charakterystyk elektrod jonoselektywnych. *IX Konferencja Naukowa Czujniki Optoelektroniczne i Elektroniczne, p. 259--262, Zakopane, 19--22.06.2006.

92. **Alicja Wiora, Józef Wiora.** *Badanie modeli dynamicznych dla elektrod jonoselektywnych o różnych rodzajach membran. *VII Polska Konferencja Chemii Analitycznej, p. 424, Toruń, 3--7.07.2005.

93. **Józef Wiora, Andrzej Krzon, Alicja Wiora.** *Porównanie modelu Nikolskiego-Eisenmana z modelem potencjału na granicy faz opisujacych potencjometryczny pomiar wieloskładnikowy. *VII Polska Konferencja Chemii Analitycznej, p. 425, Toruń, 3--7.07.2005.

94. **Józef Wiora, Alicja Wiora, Andrzej Kozyra.** *Niepewność pomiarowa współczynnika aktywności oraz jej wpływ na potencjometryczny pomiar jonoselektywny. *VII Polska Konferencja Chemii Analitycznej, p. 426, Toruń, 3--7.07.2005.

95. **Józef Wiora, Alicja Wiora, Andrzej Kozyra.** *Stanowisko pomiarowe do wyznaczania wartości parametrów dynamicznych elektrod jonoselektywnych. *V Sympozjum nt. Pomiarów Dynamicznych, p. 171--178, Szczyrk, 7--8.11.2005.

96. **Alicja Wiora, Józef Wiora.** *Wykorzystanie teorii sterowania do modelowania własności dynamicznych elektrod jonoselektywnych. *V Sympozjum nt. Pomiarów Dynamicznych, p. 179--186, Szczyrk, 7--8.11.2005.

97. **Alicja Wiora, Andrzej Kozyra, Józef Wiora.** *Celka pomiarowa do badania dynamiki elektrod jonoselektywnych. *Materiały VIII Konferencji Naukowej Czujniki Optoelektroniczne i Elektroniczne, p. 157--160, Wrocław, 27--30.06.2004.

98. **Józef Wiora.** *Rola współczynników wagowych w procesie optymalizacji parametrów kalibracyjnych elektrod jonoselektywnych. *Materiały Kongresu Metrologii KM2004, p. 653--656, Wrocław, 6--9.09.2004.

99. **Andrzej Kozyra, Alicja Wiora, Józef Wiora.** *Ocena uproszczonej procedury kalibracji parametrów elektrod jonoselektywnych wykonywanych na potrzeby pomiarów wieloskładnikowych. *Materiały Kongresu Metrologii KM2004, p. 101--104, Wrocław, 6--9.09.2004.

updated: 23.05.2024